Publication Type Journal Article
Title catena-Poly[[aquabis\4-[2-(2,4-dioxopentan-3-ylidene)hydrazin-1-y l]benzoato-kappa O\copper(II)]-mu-N,N-diethylpyridine-3-carboxamide-kappa N-2(1):O]
Authors Abel M. Maharramov Vusala I. Mardanova Famil M. Chyraqov Atash V. Gurbanov Seik Weng Ng
Groups
Journal ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Year 2012
Month February
Volume 68
Number 2
Pages M128-U485
Abstract The Cu-II atom in the title compound, [Cu(C12H11N2O4)(2)(C10H14N2O)(H2O)](n), lies in a square plane defined by the O atoms of the carboxylate ions, the N atom of the N-heterocycle and the water molecule. Coordination by an amido O atom of an adjacent N-heterocycle in the apical direction leads to a polymeric chain running along [011]. The chain motif is consolidated by hydrogen bonds involving the water molecule; the water molecule is a hydrogen-bond donor to the free carbonyl atoms of the carboxylate ions. Intramolecular N-H center dot center dot center dot O hydrogen bonds also occur.
DOI http://dx.doi.org/10.1107/S1600536812000025
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Publisher
Book Title
ISSN 1600-5368
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Conference Name
Bibtex ID ISI:000301059000033
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